Substances indicated, in 2009, as being intended to be registered by at least one company in the EEA. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). REACH registered substance data was upgraded on 9th November. … 4. 590 Revision Date: 1/8/2019 Version: 10.0 GHS Compliant . Hazardous Substances - Art. … Information on precautionary measures and the safe use is submitted by the registrant of a substance and the registrant is solely responsible for its accuracy and completeness. 11. This database contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class & category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive (2008/98/EC). endstream endobj 81 0 obj <> endobj 82 0 obj <> endobj 83 0 obj <>stream Emergency Response Guidebook 2016. 10. Substances may have impurities and additives that lead to different classifications. This section highlights four regulatory activities or outcomes under REACH – Registration, Evaluation, Authorisation and Restriction of Chemicals – Regulation (EC) No 1907/2006: Please note: The identification of relevant regulatory activities and outcomes is done automatically and without manual verification. Substances listed in the EINECS, ELINCS, or NLP inventories. REACH registration dossiers have greater data requirements (such as supporting studies) than do notifications under CLP. Other release to the environment of this substance is likely to occur from: indoor use and outdoor use resulting in inclusion into or onto a materials (e.g. Gilbert, D.C. Allport, January 2001 ... MDI methylene diphenyl diisocyanate technical MDI pure MDI diisocyanatodiphenylmethane crude MDI monomeric MDI methylenediphenylene diisocyanate polymethylene polyphenyl … Substances for which classification and labelling data have been notified to ECHA by manufacturers or importers. Some substance identifiers may have been claimed confidential, or may not have been provided, and therefore not be displayed. InfoCards are updated when new information is available. (3) MDI is the usual abbreviation for monomeric methylene diphenyl diisocyanate, (CAS# 101-68-8). The InfoCard summarises the non-confidential data of a substance held in the databases of the European Chemicals Agency (ECHA). [Note: A liquid above 99°F.] restriction on "Lead and its compounds"). Methylenediphenyl 4,4'-Diisocyanate . This is unique source of information on the chemicals manufactured and imported in Europe. h�bbd``b`� �@�q+�`��q��9� H��- � �=�P� b9 ��)�@�4�Ҍ�����$)'�3.�` ��G no data available. More information about Classification and Labelling is available in the Regulations section of ECHA website. MDA is consumed mainly as a precursor to 4,4 ́-methylene diphenyl diisocyanate (MDI). Methylene diphenyl diisocyanate; Methylenebis(4-isocyanatobenzene) Methylenebis(4-phenyl isocyanate) Methylenebis(4-phenylene isocyanate) Methylenebis(phenylisocyanate) Methylenebis(phenylisocyanate) (MDI) Methylenebis(p-phenyl isocyanate) Methylenebis(p-phenylene isocyanate) Methylenebisphenylene diisocyanate… 2(b)(i) - Hazardous Agents, Cosmetic Products Regulation, Annex II - Prohibited Substances, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, Protection of Pregnant and Breastfeeding Workers Directive, Annex I+II, Workplace Signs - minimum requirements & signs on containers and pipes, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Fertiliser Regulation- Annex I, E.3 (chelating and complexing agents), Substances of very high concern identification, Recommendation for the Authorisation List, Getting started with EU chemicals legislation, Classification of substances and mixtures, Harmonised classification and labelling (CLH). Section 1 - Identification of the substance/mixture and of the company/undertaking Brain injury, 8(3):285–294. This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. the electronic edition of the Official Journal of the European Union. Containers above RQ ship as: Agency Proper Shipping Name UN Number Packing Group Hazard Class . This substance is used in the following areas: building & construction work, health services and printing and recorded media reproduction. The number and severity of symptoms may increase. InfoCards are generated automatically based on the data available at the time of generation. … %%EOF This fact sheet is one in a series of summaries about hazardous substances and their health effects. The EC Inventory is a combination of three independent European lists of substances from the previous EU chemicals regulatory frameworks (EINECS, ELINCS and the NLP-list). Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014, EU. Methylene bisphenyl diisocyanate (MDI) INHALATION LC50-4H RAT 369.00 MG/M3 Polymethylene polyphenyl isocyanate INHALATION LC50-4H RAT 490.00 MG/M3 Methylenediphenyl diisocyanate ORAL LD50 RAT > 7,400 MG/KG INHALATION LC50-4H RAT 0.37 MG/L DERMAL LD50 RABBIT > 6,200.00 MG/KG … In order to process your orders without delay, we request that you provide the required business documentation to purchase this product. The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. Furthermore, some substances can be found in an article, but with unlikely exposure (e.g. The classifications of the substances listed in the database are based on their harmonized classifications per Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). Danger! the products in which the substance may be used) may refer to uses as intermediate and under controlled conditions, for which there is no consumer exposure. • MDI and TDI Nomenclature, Gilbert International Limited 2001, GIL Report Number 2001/B, B. Tury, D.S. A prioritisation hierarchy means that data is taken from harmonised C&L data and regulatory lists first, then REACH registrations and finally from CLP notifications. The “UN Sub-committee of Experts on Transport of Dangerous Goods” decided in July 1994 to remove Diphenylmethane Diisocyanate (MDI) from the list of hazardous goods. If the substance was not covered by the EC Inventory, ECHA attributes a list number in the same format, starting with the numbers 6, 7, 8 or 9. Biocidal Products Committee opinions on active substance approval, National authorisation and mutual recognition, Understanding the Waste Framework Directive, Tools to prepare and submit SCIP notifications, List of substances subject to the POPs Regulation, Draft recommendation for inclusion in the Authorisation List and consultation, Submitted restrictions under consideration, Harmonised classification and labelling targeted consultations, Consultations on ECHA Executive Director’s requests, PACT - Public Activities Coordination Tool, Information on Candidate List substances in articles, Candidate List of substances of very high concern for Authorisation, Registry of restriction intentions until outcome, Registry of SVHC intentions until outcome, Table of harmonised entries in Annex VI to CLP, Occupational exposure limits - Activity list, Harmonised classification and labelling (RAC), Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment, Candidate list of substances of very high concern for authorisation, Guidance on the safe use of the substance, PACT - Public activities Co-ordination Tool, Persistence, bioaccumulation and toxicity assessment, RMOA - Regulatory Management Options Analysis, CAD - Chemical Agents Directive,Art. Substances potentially subject to further regulatory management. Note that this list is not exhaustive. The POPs Regulation bans or severely restricts the production and use of persistent organic pollutants in the European Union. Details of dossier compliance checks and testing proposal evaluation. Methylene Diphenyl Diisocyanate (monomeric MDI) and polymeric MDI (PMDI) CASRN 101-68-8, 9016-87-9 | DTXSID7025180 Chemical Agents: Annexes I & II, Dir. First-aid measures Action Plan [RIN 2070-ZA15] I. Overview . Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. Please upgrade your Internet Explorer to a newer version. When information is available in all sources, the first two are displayed as a priority. Stability and reactivity 10.1 Reactivity. ��#�Y^�7��b�4.F��}��:WI���1w�y�(_W�q2.H�������e�B�r�|�I��|>�Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����. IDH number: 1506861 Product name: LOCTITE HB E202 known as PURBOND HB E202 Page 6 of 6 International Air Transportation (ICAO/IATA) This substance has been identified as member of the following groups of substances: Welcome to the ECHA website. Substances for which certain uses are Restricted under REACH at EU level. This substance is used in the following products: coating products, inks and toners, polymers and cosmetics and personal care products. 6(6), Reg. These notifications can be provided by manufacturers, importers and downstream users. Methylenediphenyl 4,4 -Diisocyanate 97.0 %, TCI America 25G Chemicals:Organic Compounds:Benzenoids:Benzene and substituted derivatives:Diphenylmethanes EU. It is not soluble in water. Release to the environment of this substance can occur from industrial use: formulation of mixtures, formulation in materials, for thermoplastic manufacture and in the production of articles. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. LEL:. The ‘Properties of concern’ section shows ECHA-assigned graphical indicators for certain substance properties that are regarded as being of relevance or importance to human health and/or the environment based on the information provided to the Agency. This fact sheet answers the most frequently asked health questions (FAQs) about toluene diisocyanate (TDI) and methylenediphenyl diisocyanate (MDI). Stable under recommended storage conditions. Lower quantities are used as hardeners in epoxy resins and adhesives, as well as in the production of high-performance polymers. Substances for which an agreed set of classification and labelling data has been agreed at EU level by Member States. To order chemicals, medical devices, or other restricted products please provide identification that includes your business name and shipping address via email [email protected] or fax 484.881.5997 referencing your VWR account number . 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. disodium tetraborate EC no. Gas concentrations are in percent by volume. ECHA has no public registered data on the routes by which this substance is most likely to be released to the environment. A substance identified primarily by an EC or list number may be linked with more than one CAS number, or with CAS numbers that have been deleted. Release to the environment of this substance can occur from industrial use: for thermoplastic manufacture, in the production of articles, in processing aids at industrial sites, formulation of mixtures, formulation in materials and as an intermediate step in further manufacturing of another substance (use of intermediates). This substance is used in the following areas: formulation of mixtures and/or re-packaging. The content of monomeric MDI generally is between 45% and 65% on a w/w basis (Mobay, 1983). 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) White to light-yellow, odorless flakes. To confirm if a substance is covered by a specific regulatory action the official publication, e.g. REACH Annex XVII. h�b```f``�d`e`�p``@ �(GCT䎒��N]���eX2�v2�aig�e`H�����l R�,����`�Wa��fH�l�۶��ʚå���PB+!� cEsE�[EGG�y{sxGP���+�*p���Ӟ ia � ��2�3,�[�3A_!��&i�Lf�����x��xO�%0�Hi: ���y@����X����"�Ϩ ` �3?# This website uses cookies to ensure you get the best experience on our websites. The Prior Informed Consent Regulation administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries. Product Number: D0897: Purity / Analysis Method >97.0%(T) Molecular Formula / Molecular Weight: C__1__5H__1__0N__2O__2 = 250.26 : Physical State (20 deg.C) Solid: Storage Temperature: 0-10°C: Store Under Inert Gas: Store under inert gas: Condition to Avoid: Moisture Sensitive,Heat Sensitive: CAS RN: 101-68-8: Reaxys Registry Number… Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements (EUH) or the. The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Manage accidents and report an accident in accordance with all local, state and federal regulations. CAS number: 101–68–8 NIOSH REL: 0.05 mg/m 3 (0.005 ppm) TWA, 0.2 mg/m 3 (0.020 ppm) 10-minute CEILING. MDI and other isocyanates may also cause hypersensitivity pneumonitis, another allergic lung ... Methylene diphenyl diisocyanate (MDI) 0.051 (0.005 ppm) 0.2 (0.02 ppm) 0.005 ppm . The precautionary measures and guidance on safe use are as submitted to ECHA by registrants under the REACH Regulation. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. 80 0 obj <> endobj If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. This directive requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use. This list contains substances to which pregnant workers and workers who have recently given birth or are breastfeeding may not be exposed. This information has not been reviewed or verified by ECHA, and may change without prior notice. Note that this list is not exhaustive. The per substance REACH registration status is being calculated and will be made available as soon as possible. This is only a partial list; employers are obliged to prevent the exposure of these workers to any agents that may cause adverse health effect for either mother or child. The “polymeric” forms of MDI, which typically consist of 30-70 percent monomeric diphenylmethane diisocyanate and the balance in higher molecular weight fractions (CAS # 5873-54-1) may at times be generically … The molecular structure is based on structures generated from information available in ECHA’s databases. The EC or list number is the primary substance identifier used by ECHA. Here you can find all of the regulations and regulatory lists in which this substance appears, according to the data available to ECHA. 117 0 obj <>stream 2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. The type of uses and classifications may vary between different submissions to ECHA and for a full understanding it is recommended to consult the source data. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. Polymeric Diphenylmethane Diisocyanate (pMDI) 9016-87-9 50 – 60 4, 4’ Diphenylmethane Diisocyanate (MDI) 101-68-8 35 – 45 2, 4’ Diphenylmethane Diisocyanate (MDI) 5873-54-1 1 – 5 SECTION 4: FIRST AID MEASURES Eye Contact Immediately flush eyes with running water for a minimum of 15 minutes. 2(b)(i) - Hazardous Agents, Protection of Pregnant and Breastfeeding Workers Directive, Annex I+II, Workplace Signs - minimum requirements & signs on containers and pipes, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Fertiliser Regulation- Annex I, E.3 (chelating and complexing agents), C&L Inventory, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, 4,4'-diisocyanate de diphénylméthane (fr), 4,4'-Metyleenidifenyylidi-isosyanaatti (fi), difenyylimetaani-4,4'-di-isosyanaatti (fi), diisocianato de 4,4'-metilendifenilo (es), diisocianato de 4,4'metilenodifenilo (pt), diisocianato di 4,4'-metilendifenile (it), diisocyanate de 4,4'-méthylènediphényle; diphénylméthane-4,4'-diisocyanate; (fr), diizocyjanian 4,4'-metylenodifenylu) (pl), διισοκυανικό 4,4'-μεθυλενοδιφαινύλιο (el), 1-isocyanato-4-(4-isocyanatobenzyl)-benzeen, 1-isocyanato-4-[(4-isocyanatophenyl)methyl] benzene, 1-isocyanato-4-[(4-isocyanatophenyl)methyl]benzene, C&L Inventory, Registration dossier, Other, 4,4'-methylenediphenyl diisocyanate1,1'-methanediylbis(4-isocyanatobenzene)1,1'-methylenebis(4-isocyanatobenzene)1-isocyanato-4-[(4-isocyanatophenyl)methyl] benzene1-isocyanato-4-[(4-isocyanatophenyl)methyl]benzene4,4 - methylenediphenyl diisocyanate4,4 methylenediphenyldiisocyanate4,4'-DIISOCIANATO DE DIFENIL-METILENO4,4'-Diisocyanatodiphenylmethane4,4'-DIPHENYLMETHANE DIISOCYANATE4,4'-Methylendiphenyl diisocyanate4,4'-Methylenediphenyl diisocyanateBenzene, 1,1'-methylenebis[4-isocyanato-difenylmethan-4,4'-diisokyanátDiisocyanate of 4,4 '-methylenediphenylDiphenylmethane diisocyanateDIPHENYLMETHANE-4,4'-DI-ISOCYANATEdiphenylmethane-4,4'-diisocyanateMDI, MMDI, Pure >MDI, rein MDI, 4,4'-MDI,MDI, MMDI, Pure MDI, Rein MDI, 4,4`-MDIMethylene diphenyl diisocyanateMethylenediphenyl 4,4'-Diisocyanate. , 28 November 2019, EU close find out more on how to use them.... 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