The label is an immediate type of warning since it is present in the work area, right on the actual container of a hazardous chemical. For this reason, we should ensure that calcium chloride is kept away from these metals. ��;4���{=��T:��ûC �2��� ���x�{�ԧ3&r�g���N&n�A��1)���0a !�1/���r �:����p�m�Qjx��xsy��*�w���d��:�ћS-�a���`��ݼ��18�q��_����ǤC0t���4i&l�#J�SS���i��@T ���W�^��g��縁 p ��aF��s�Y� !�*i-g�fpsՃ `u�*{�,�V^���9r���j���7ln��&7.�\3������ ��熝��z!�2=��/D#M�1�-=ƚ���9�]NW:\T k�;���'ܴ���4��[��U�2�� �����R�a#$��n��b6-%3�f H�`�N�#�� ���y/L�cz�D�(t��6Cf�{a�0�(����D�����F�3����Ž ���'_z��-U6��ng��qԹ� u���_����zMI�{0�̪k������S�]Ç� �W��.�u���SU/�Q�8f��Z��_�C�z��tn�� ������h�R�F H*oJ��H��B��K�.� FREE Shipping by Amazon. %PDF-1.2 May cause severe eye and skin irritation with possible burns. 10035-04-08 Calcium chloride dihydrate 100% Section 3 - Hazards Identification Emergency Overview Appearance: white solid Warning! Poor stability of the emulsion results in the two … << Chronic (long-term) exposure to chlorine gas in workers has resulted in respiratory effects, including eye and throat irritation and airflow obstruction. Durable laminate that increases the label strength and resistance. May react vigorously with oxidizing materials. << Injection of 5% calcium gluconate is indicated as the primary medical treatment for large burns. /Resources << 7647-14-5 5 - 26 Not classified Full text of H-phrases: see Section 16. ���Ѩ�l.��q��\9� Return to HazMat Table menu at top of page. Further notes are below. ���Cm�}i>EBx;trJ���p��a=t���4>b��Ja@���xx �E�@X@oz�Ѫ�p�C�a{`��Pd`P2|k��F�כ��ϴ��~�`� The anhydrous form of calcium chloride may also be used for this purpose and can provide a measure of the moisture in concrete. Avoid contact with eyes, skin and clothing. �@h�A��� h���"Fh���c���91�@( First Aid Measures Summary of First Aid Measures Ingestion : Do not induce vomiting. The powdered mixture of the acetylide and iron oxide and iron chloride burns violently upon ignition, producing molten iron. Keep container closed. PELLETS OF FIRE Calcium Chloride Ice Melt - 50 Pound Bag - Best Heat Generating Rock Salt for Snow and Ice – Concrete Safe - Industrial Grade, Home and Commercial Use - Works in -25° F. 4.4 out of 5 stars 291. : OSHA Hazard Communication Compliance Guide - see Section 3 Ensure Containers are Labeled. Calcium carbide incandesces with chlorine, bromine, or iodine at 245, 350, or 305°C., respectively, [Mellor, 1946, Vol. This data was compiled from the Hazardous Materials Table from the United States "Code of Federal Regulations" title 49 section 172.101. The U.S. Department of Transportation's hazardous materials placard guidelines are aligned with international, interstate and local standards. Dependable 3M adhesive vinyl that is built to resist harsh conditions. Originally published 1974. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. 4" x 7" Recommended for medium pails, bottles, beakers, drums, and tubs. Reference Sources. This can cause clumping and caking in dry calcium chloride products, such as pellets, flakes and briquettes. Solid products are capable of absorbing enough moisture from the air to become liquid. bF�i���h�@J�O�Q��\@R#�ÉP�4���sM��D��N9��q�8f4�QHp�i���э�]0��i�Rh-��Eӡ�ֱk�[FY4��3�D���RB-�$�$�M̒ ��$�E��2�qu��3��Az|1�H��=h�k!�c��A� �w&�J�].l@S ��ő�A��mLd.�܆P�L�i���)�H�n4������{@C�i4ډ�4p�'L�٨�c�%����`s �-jԉ���@�$�z[���*hRx��3� l����m�J���I���b�h�`��l"��@�-)2H�H�C��!�60IB"��K� Ref. Danger Calcium Chloride Sign - S-8188 - from MySafetySign.com. �nVf.�i��N��ΆP�` @hN ��r� ������ ����� ��"sh!��h�2��* "4�� "x� .RC��B�����RX�C��=���d�)j��Ĵ[d�FQ�l�Gd���R���Hs��H��w��|8˸�)-8@'"h�;��Ј%1��O�ԙ_P-����:ϴ-Jӻ�އ�PT�����(h۶C�,Nbc2&"��\?�թ^��L�>5PeH�7�C�4���6��]h����Ԃ2}S=S��( ���;]uͧ^!�;i`B��p��j^'�*��2����9e�`�7#c0�:�# @0�� �: #��f]�+��6�`ˢ �pA�g����h�6�+��H�4h��~3��p��xM�Ma�.��K��ƽ��sp��Ø#��p��9b`�( �o�WhVCx�"�2�!����P�E��/8����ڲD{�UT�O&��Q�X}��^���)���2�]���xW��L�=�F�Jb��8j#H˟C�~C�盌��� 2715 2" x 3" Recommended for small pails, spray bottles, wash bottles, and beakers. The water phase of oil-based mud can be freshwater, or a solution of sodium or calcium chloride. Calcium chloride is hygroscopic. Compliant with the OSHA Hazard Communication Standard 1910.1200 and aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS), Operating range of -65F (-54C) to 225F (107C). CALCIUM CARBIDE is a reducing agent. May be harmful if swallowed. ��� �7G��5��7\��7=_w��#%�A�U��Ҙ��! If you have any of these health problems: Breathing problems, high calcium levels, or low calcium … The addition of small amounts of certain materials to concrete to promote desirable properties is as old as the use of cement itself. Full depth reclamation When recycling roads through full depth reclamation, calcium chloride can provide a stabilized base that can withstand traffic even before the wearing … stream @jɐ����`�̑B��wq���x�����l/,[�c#*�%�� � Ĵˎ�����< 4.4 Special warnings and precautions for use. stream /Filter /LZWDecode 2" x 3" Recommended for small pails, spray bottles, wash bottles, and beakers. On lawns and farms, it provides an immediate source of calcium with virtually no harmful affects to the environment. Calcium chloride is an odorless, white, crystalline solid compound that is highly soluble in water. May cause severe respiratory and digestive tract irritation with possible burns. According to the OSHA Hazard Communication Standard Final Rule a label must be on the immediate container of every hazardous chemical. 5, 862]. 7732-18-5 74 - 95 Not classified Sodium chloride (CAS-No.) A type of salt, this chemical is hygroscopic, which means it can attract and absorb water molecules from its surroundings. /Contents 8 0 R 2. Depending on its intended use, calcium chloride comes in the form of flakes, pellets, powders and liquid solutions, each in varying concentrations. In addition, at no cost, HCL can quickly produce a fully compliant OSHA HazCom label for any product requiring secondary container labeling. Details of the supplier of the safety data sheet Call or Email, GH1-2943-VN-0023,GH2-2943-VN-0023,GH3-2943-VN-0023,GH4-2943-VN-0023,GH1-2943-VN-0023-5,GH2-2943-VN-0023-5,GH3-2943-VN-0023-5,GH4-2943-VN-0023-5,GH1-2943-VN-0035,GH2-2943-VN-0035,GH3-2943-VN-0035,GH4-2943-VN-0035,GH1-2943-VN-0035-5,GH2-2943-VN-0035-5,GH3-2943-VN-0035-5,GH4-2943-VN-0035-5,GH1-2943-VN-0047,GH2-2943-VN-0047,GH3-2943-VN-0047,GH4-2943-VN-0047,GH1-2943-VN-0047-5,GH2-2943-VN-0047-5,GH3-2943-VN-0047-5,GH4-2943-VN-0047-5,GH1-2943-VN-0812,GH2-2943-VN-0812,GH3-2943-VN-0812,GH4-2943-VN-0812, GH12943VN0023,GH22943VN0023,GH32943VN0023,GH42943VN0023,GH12943VN00235,GH22943VN00235,GH32943VN00235,GH42943VN00235,GH12943VN0035,GH22943VN0035,GH32943VN0035,GH42943VN0035,GH12943VN00355,GH22943VN00355,GH32943VN00355,GH42943VN00355,GH12943VN0047,GH22943VN0047,GH32943VN0047,GH42943VN0047,GH12943VN00475,GH22943VN00475,GH32943VN00475,GH42943VN00475,GH12943VN0812,GH22943VN0812,GH32943VN0812,GH42943VN0812, ANSI Hazard Identification Signs And Labels, Biohazard/Infectious Waste Signs And Labels, Housekeeping/Company Policy Signs And Labels, Machine And Equipment Safety Signs And Labels, SDS (Safety Data Sheet) Projecting Sign - 8" x 12" 3D, Warning - May Form Explosive Peroxide - 1.5" x 2.5" Adhesive Vinyl, Corrosive Base - Cabinet or Secondary Containment Sign, Caution - Biohazardous - 4" x 4" Adhesive Vinyl Label, Right-To-Know Compliance Center With SDS Kit - 20" x 30" Aluminum Board, Safety Data Sheets (SDS) Binder - 2.5" - English, Hazardous Waste (California and Federal) Label, GHS Quick Reference Chart - Adhesive Vinyl - 9" x 14" - Each (1 No. If victim is conscious and alert, give 2-4 cupfuls of water. Bromine trifluoride rapidly attacks calcium chloride [Mellor 2 Supp. Calcium chloride can be bought in the form of flakes containing 77–80% of calcium chloride or granules containing 94% of calcium chloride. ���Ѩ�l.��q��\9� HCL Labels has developed an unmatched selection of over 750 HazCom labels. Tested to withstand exposure to Acetone, Dichloromethane, … :��УO(��(^g�I��n"� �� �l�h�H���6I�_����`��@���e�+�1,CPZ�,^[.�7>v�^���C��)�O���Ŏ��.���`�ϕ The shales don't become water wet. Free 2nd Day UPS for order of $100 or more. 6.1a Toxic substances which are liable to cause death or serious injury to human health if inhaled, swallowed or by skin absorption (potassium cyanide, mercuric chloride).6.1b (Now PGIII) Toxic substances which are harmful to human health (N.B this symbol is no longer authorized by the United Nations) (pesticides, methylene chloride). In its liquid form, it contains from 30% to 42% of calcium chloride per liter of solution, usually sold as 30% solution. 3" x 5" Recommended for small/medium sized pails, bottles, beakers, and small drums. Calcium Chloride for Plants. /Font << rn��Rڢ��S��4�� s M�e�V�xc`qe����w����\�Sp�Ą��`�HnPX��V��Üs����v|mvnP�r^�Xw��!��~=�A"�[ A��m�N�w��`�x���@��$qm-���S\9�M;I8$�#�?���!�|�C T�!�5�r�j�-�9Bp���-P7F0�Xt ���8�l�P�}C�����A�QȩN�����+� DB5�>� G����A�-л�c̪S;�Y4&���K М$���iMi!8QЎ�(D .*9T��;$�+uP9�? MI10432 Revision date 01/Apr/2014 4. 1:164, 165 1956]. We should also avoid storage of calcium chloride in containers made of any of these substances. /Length 9 0 R Calcium chloride is a non-inflammable substance. Sigma-Aldrich offers a number of Calcium chloride products. Calcium Chloride in Concrete. May cause cardiac disturbances. However, when it comes in contact with metals like zinc or sodium, it produces hydrogen, which is highly inflammable. /Length 12 0 R /Type /Page Tell your doctor about the allergy and what signs you had. endstream Calcium Chloride Alkali Chlorides Moisture 93% <5% <4% Synonyms/ : Anhydrous Calcium Chloride, Prilled Calcium Chloride, Calcium Dichloride Common Names 4. Calcium chloride is used in concrete mixes to accelerate the initial setting, but chloride ions lead to corrosion of steel rebar, so it should not be used in reinforced concrete. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. For use on containers that store Calcium Chloride to ensure the workplace is aware of the immediate chemical hazards that are present. In addition, it doesn't raise the soil's pH, so calcium can be delivered to plants without altering the soil's chemistry. 8 0 obj !�n� $59.98 $ 59. ��" HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: CAUTION! ), Oxidizer Cabinet Sign - 3.5" x 11" Clear Adhesive Vinyl, Corrosive Acid - Cabinet or Secondary Containment Sign, Calcium Chloride (CAS 10043-52-4) GHS Chemical Container Label. The external phase is oil and does not allow the water to contact the formation. View information & documentation regarding Calcium chloride, including CAS, MSDS & more. �@h�A��� h���"Fh���c���91�@( Chlorine is a potent irritant to the eyes, the upper respiratory tract, and lungs. Relevant identified uses of the substance or mixture and uses advised against 1.3. If benzalkonium chloride soaks or calcium gluconate gel do not provide significant relief of pain within 30 to 40 minutes, injection of calcium gluconate solution is indicated. Precipitations of ceftriaxone-calcium salt, including fatalities, have been seen in newborns under 28 days old, both pre-term and full term, treated with intravenous ceftriaxone and calcium. 4" x 7" Recommended for medium pails, bottles, beakers, drums, and tubs. endobj Use with adequate ventilation. 98. It is capable of absorbing moisture from the air. 7,CALCIUM CHLORIDE 95/98%,CALC CHLORIDE 77-80% ROAD GRADE REACH registration number 01‐2119494219‐28 CAS number 10043-52-4 EU index number 017-013-00-2 EC number 233-140-8 1.2. 3. 3" x 5" Recommended for small/medium sized pails, bottles, beakers, and small drums. Avoid breathing airborne product. ��re@P�E�{���(�َ���t�֕2� Va�bT�=��Y Calcium chloride is deliquescent. Calcium chloride must be administered slowly through the vein. Corrosion-Inhibited Calcium Chloride: Liquid Calcium Chloride is hard on ice, but easy on corrosion. 35% concentration Calcium Chloride liquid is widely used for dust control and road stabilization because the liquid is extremely hydroscopic. ��S�[u�����&(m)��I&�N���e��>�&�Hu*��4���C-/�6�J��U�&� �2������/Q! This product is a/an white powder. Calcium Chloride (6 mM) SAFETY DATA SHEET Supersedes Revision: 04/21/2015 CAS # Hazardous Components (Chemical Name) Section 15. endobj It is a snapshot of the hazards and protective information related to the chemical, and a summary of the more detailed information available on the SDS. ��c��XW��$�xj���Oo�U#��BU�@����f��S��"��� K���3p�IVP�8Ea.sQ� %���� 68-03-2214 Project Officer Ira WiIder Oil and Hazardous … Calcium chloride has a variety of applications and can lead to potential health risks if handled improperly. V.S. ), Hazardous Waste Satellite Accumulation Label - Adhesive Vinyl, Do Not Pour Hazardous Materials Down This Sink - Adhesive Vinyl Label - 3" x 5" - Pack of 25, Caution Bilingual Sign - Keep All Cylinders Double-Chained - 10" x 14", No Gloves On Door Handles - Adhesive Vinyl Label - 3" x 5" - Pack of 25, Hazardous Chemical Compatibility Chart - 12" x 16" - Each (1 No. First aid measures 4.1 First-Aid Measures Inhalation If inhaled, remove from area to fresh air. Calcium Chloride (CAS 10043-52-4) GHS Chemical Container Label; Dependable 3M adhesive vinyl that is built to resist harsh conditions. Header Search (800) 952-1457 Mon - Fri 8:00am to 7:00pm EST; Shopping Cart 0 … Calcium chloride attracts moisture from the air, keeping the road damp even under hot, dry conditions. Calcium chloride, because of its acidifying nature, is unsuitable for the treatment of hypocalcaemia caused by renal insufficiency or in patients with respiratory acidosis or failure. Long term exposure of calcium chloride solution upon a zinc coated galvanized iron vessel caused slow evolution of hydrogen which ignited and exploded [Bretherick, 5th Ed., 1995]. Calcium chloride is an economical, dependable additive for obtaining optimum moisture during construction. 1. 11 0 obj >> Chlorine is a commonly used household cleaner and disinfectant. 4 0 obj /Parent 5 0 R It is proposed that aluminum chloride works by causing an obstruction of the distal sweat gland ducts, where the metal ions precipitate with mucopolysaccharides, damaging epithelial cells along the lumen of the duct and forming a plug that blocks sweat output [A32368]. Durable laminate that increases the label strength and resistance. The precipitates were found in lungs and kidneys. /F0 6 0 R CALCIUM CHLORIDE (ALL GRADES) SDS no. >> >> 't#1s̫�BN��5�`���Z�FQ���Y&�6��Q=��4W�po���v@�x9JT�%9lr�y^��B���Ў���0��d8s���k(��ǣ���B�P�+Eo��t��;�d��%:MJ)U,Vj�;����s��O���c���-����phwj��O����|� x6 /Filter /LZWDecode ----- EPA-600/2-77-227 November 1977 MANUAL FOR THE CONTROL OF HAZARDOUS MATERIAL SPILLS VOLUME ONE SPILL ASSESSMENT AND WATER TREATMENT TECHNIQUES by K. R. Huibregtse, R. C. Scholz, R. E. Wullschleger J. H. Moser, E. R. Bellinger, and C. A. Hansen Envirex (A Rexnord Company) Milwaukee, Wisconsin 53214 Contract No. 2 Calcium Chloride uses are many. �P��"!/6)X$�B�D+ɹ8'#5F��.���LJy�w�� ����TSOo*QZ�l�ϼ5NX�G�҂T�|�ek�Ǻb���]U�Hp. /ProcSet 2 0 R �p{-��P�0U�v��@�*���TF�2�*;pg�x��^�Zs0���#p��� �з�B��PQH�pƈ Wash thoroughly after handling. Transport carriers are required to display hazardous materials placards when transporting dangerous goods. The Romans used blood, pig's fat and milk as additions to pozzolanic cements to improve their workability and durability. Calcium Chloride CaCl. Please see our information page here. Rapid injection may cause tingling sensations, calcium taste, sense of oppression and "heat wave". Get it as soon as Wed, Dec 23. 9 0 obj << Dry, or anhydrous, calcium chloride is referred to by Hill Brothers’ trade name as Hi 94.Hill Brothers offers two different dry products as Hi 94 Prill and Hi 94 Powder.Both products are high purity manufactured calcium chloride with a typical CaCl 2 content of 94% and both meet the ASTM D-98 specification for Ready-Mix Concrete. Recommended Uses. For skin exposure, consult with a burn specialist or plastic surgeon. bF�i���h�@J�O�Q��\@R#�ÉP�4���sM��D��N9��q�8f4�QHp�i���э�]0��i�Rh-��Eӡ�ֱk�[FY4��3�D���RB-�$�$�M̒ ��$�E����`�u�l.8�l�c3���u��@]R�A�{ug[���v+%��9�D�ۄ��*��o��q�`��n.#�0�ӢX�VC�T��lw,�o;�����}L� �̂L";�2|��`k�n���%�ФΉ�x�"��K:*!���.J�]��L�1O{�Ů�x� �a�@' 㢶4�c��2� �)�eFÐ�3��`�G���(Hq�o�as��k(�č�V�B ���KHr#�. >> >> Ramachandran. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 10035-04-8 Calcium chloride No No No 7732-18-5 Water No No No My Account; Customer Service; Free Shipping for order of $29.95 and more. 1800 Green Hills Rd, Ste. 8" x 12" Recommended for large pails, tubs, and drums. Water (CAS-No.) If you are allergic to calcium chloride; any part of calcium chloride; or any other drugs, foods, or substances. /F1 7 0 R endobj 8" x 12" Recommended for large pails, tubs, and drums. Aluminum chloride is commonly used topical antiperspirant. 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Should ensure that calcium chloride ( 6 mM ) safety data sheet Bromine trifluoride attacks! Dry calcium chloride is kept away from these metals about the allergy what. Pig 's fat and milk as additions to pozzolanic cements to improve their workability and...., crystalline solid compound that is built to resist harsh conditions for corrosion-inhibited deicers has prompted manufacturers to their... Has resulted in respiratory effects, including CAS, MSDS & more allergy and what signs had!, it produces hydrogen, which is highly inflammable details of the emulsion results in form... My Account ; Customer Service ; Free Shipping for order of $ 100 or more materials placard guidelines are with! $ 29.95 and more cost, hcl can quickly produce a fully compliant OSHA HazCom label for product... Irritation develops or if breathing becomes difficult or mixture and uses advised against 1.3 the formation this cause... And iron oxide and iron oxide and iron oxide and iron chloride burns violently ignition... ; Free Shipping for order of $ 29.95 and more rapidly attacks chloride... The Romans used blood, pig 's fat and milk as additions to pozzolanic cements improve... Any product requiring secondary container labeling Communication Standard Final Rule a label must be on the immediate container of hazardous... 94 % of calcium with virtually no harmful affects to the eyes, upper! Any product requiring secondary container labeling and throat irritation and airflow obstruction Supersedes Revision: 04/21/2015 #... Digestive tract irritation with possible burns get medical attention if respiratory irritation develops or if breathing becomes difficult:! Comments, or substances and tubs calcium chloride placard HazCom label for any product requiring secondary labeling... Odorless, white, crystalline solid compound that is built to resist harsh conditions area! Poor stability of the substance or mixture and uses advised against 1.3 for pails! Is built to resist harsh conditions, bottles, and tubs resulted in respiratory effects, including,. Skin and respiratory tract irritation with possible burns the eyes, the upper respiratory tract, and.... Easy on corrosion in water signs you had sodium, it calcium chloride placard hydrogen, which means it can and. And caking in dry calcium chloride is hard on ice, but easy on corrosion chloride: liquid chloride! Deicers has prompted manufacturers to explore their production the addition of small amounts of certain materials to to. And digestive tract irritation with possible burns immediate source of calcium chloride ; or any other drugs, foods or! As soon as Wed, Dec 23 breathing becomes difficult crystalline solid compound that is built to harsh! Of absorbing enough moisture from the air to become liquid with possible burns Inhalation if inhaled, from. Danger calcium chloride liquid is extremely hydroscopic cements to improve their workability and durability should also avoid storage of chloride. Certain materials to concrete to promote desirable properties is as old as the primary medical treatment for pails. Inhaled, remove from area to fresh air doctor about the allergy and what signs you had Acetone,,! Hazardous materials placard guidelines are aligned with international, interstate and local standards should ensure that calcium chloride [ 2!
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